toluene high reddit

The crystals that form are n-iso though, so the remaining liquid would have to be poured off and evaporated. The toluene-rich bottom phase could be later redistilled, to improve its purity. level 2. You guys all know that you can make chloroform by adding a very small amount of acetone to very cold bleach, right? It is soluble in isopropanol, just not nearly as soluble as it is in water, ethanol, or methanol. As far as solvents go, I also have methyl ethyl ketone and limonene. The joint got me high as hell. Toluene is a widely used industrial solvent, and humans may also have high exposures to toluene from the deliberate inhalation ("sniffing") of paint reducer, paint thinner, or paint for their narcotic effects. Page 2 of 16 MSDS - Toluene POTENTIAL HEALTH EFFECTS Repeated exposure may cause skin dryness or cracking. Although flat, layered n-iso crystals didn't form from the water layer, that doesn't mean there weren't any there, among other things. I keep all the cut meth I end up with in jarsfisnt Aror testing shit like this I call thm go yg if b . Why has toluene (111°C) a higher boiling point than ethanol (78°C)? However, you're welcome to keep reading if you're interested in perhaps removing the levo part. So, I boiled the water layer mixed with isopropanol until it started to look like there wasn't that much solvent left, then left it sit to cool off. XS5250000. I'll use toluene as a solvent to conduct reflux experiment, however, my reactant is decomposed under high-temperature condition around 100 oC. It was an enjoyable and different high. Bin Zhu, Lu-Yao Zhang, Meng Li, Yan Yan, Xiao-Min Zhang, Yi-Min Zhu, High-performance of plasma-catalysis hybrid system for toluene removal in air using supported Au nanocatalysts, Chemical Engineering Journal, 10.1016/j.cej.2019.122599, (122599), (2019). When I went to shake the hot mix in the stoppered test tube, the entire contents blew out like it was new year's eve. For example, let's say it looked good; cloudy, waxy, heavy, dense, bitter; lines going in same direction. If swallowed, may be aspirated and cause lung damage. All their physical properties are the same too. If I only order a small amount for comparison and testing? Either way I will gladly take racemic/not as potent meth over this ISO bullshit any day of the fucking week! I hope you speak truth, for it has been the darkest of days here in the gacklands. It'd be a cold day in hell if his shit was the real deal. Toluene is a common solvent, especially in spray paint. Xylene and toluene are not available where I live. The key to separating them seems to be the higher affinity that methamphetamine HCl has for water. I actually added isopropyl alcohol to the water layer (I used 100% concentration, but 90-91% should work well too.) Abstract. Basically, I just meant that adding isopropanol will allow crystals to form more easily due to a change in temperature, whereas if you just had straight water, it'd probably all stay in solution, even if it was cold. Cheers! Basically, they're identical structurally, but one is a mirror image of the other. Toluene. Another solvent mixture that might work is dissolving it in chloroform or methylene chloride (dichloromethane) and then adding water and shaking really well for a long time. Toluene occurs naturally in crude oil and in the tolu tree. NFPA Hazard ID: Health: 2 Flammability: 3 Reactivity: 0 (1) Toluene exposure may also occur in the workplace, especially in occupations such as printing or painting, where toluene … This is expected though, since you actually have a mixture (of dextro and levo meth) rather than a pure substance, and only pure substances will solidify in a wave. However, the few times they mention the synthesis, they only ever mention methods that are NOT stereoselective, which I guess means the show should have had better science advisors. But really, who the fuck cares? For the treatment of toluene exhaust gas, absorption is widely applied because of its advantages of mature technology and high efficiency, and research for the development and performance of absorbents is one of the focuses in this field. Wait, I guess I have a third general chemistry question. Let's say I acquired a questionable 4 grams under suspicious circumstances from my regular guy. Ethanol can make hydrogen bonds and has a large dipole moment (1.7D), whereas toluene only has a dipole moment of 0.36D. ... Get high-quality answers from experts. Second; I have vm&p naphtha. It's quite subtle, but eventually it's pretty easy to notice, and with experience, will produce a gag reflex of sorts. Some of the additional effects of toluene include the following: Eye and nose irritation How do I know in advance which one to use for different applications? Also, because they don't quite fit together with each other, they'll only form crystals when the two enantiomers/stereoisomers are segregated from each other. I have heard of limonene being used at some pint on the manufacture of, producing what some have called "lemon drop". A small amount dissolved in a few drops of isopropanol, when left to evap (on a glass desk), seems to form a homogeneous pattern. As a leading supplier of high-purity solvents, we have the right toluene to meet your needs. I still won't sell it since n-iso is not the only cut I come across, Theres research chemicals galore in there, but if this works then I might be able to salvage something decent next time one of my suppliers gets shady. Still, auto body shops and specialty paint shops will often sell it, it's easy enough to get online, and if you absolutely needed to, you could probably distill it from spray paint or something, which is something that I, in no uncertain terms, do not recommend. Methamphetamine hydrochloride is not very soluble in isopropanol, so if I could boil away most of the solvent and let it sit and cool off, I could observe the crystals that formed. When I was in high school I always got it confused with phenol, which is what "toluol" would logically mean. The active ingredient is TOLUENE, not acetone, you should avoid acetone as it merely tastes bad, (no hallucinations). I do know however that when I would isolate and recrystallize DMT, xylene, naphtha, and limonene could all be used to great effect and were essentially interchangeable. London dispersion forces can be very strong when you are dealing with lots of electrons, saying they are weak is only true when you are exclusively talking about small highly polar molecules. An autoclave is described which has a variable internal sample volume. I will try when I get out of the hospital. Reason being, it's really annoying to try and characterize crystals that form from boiling water away, and just evaporating the water at room temperature takes a long time. New comments cannot be posted and votes cannot be cast. A highly regio‐ and stereoselective syn‐carbometalation of terminal secondary or tertiary propargylic alcohols with primary alkyl Grignard reagents in toluene or phenylmagnesium bromide in Et 2 O was developed, in which the alkyl or phenyl group from the Grignard reagents is introduced into the terminal position of the alcohols. I'm writing to ask for any publication which has a method for iodination of toluene specific and must give high yield and be environmental friendly. A similar solvent, xylene, is easier to find on shelves and would probably work, but I didn't test it, and so I don't know for sure. The highest concentrations of toluene usually occur in indoor air from the use of common household products (paints, paint thinners, adhesives, synthetic fragrances and nail polish) and cigarette smoke. Toluene is a common solvent, especially in spray paint. If I look to the intermolecular forces, I would think that it was the other way around. Related Pages. (For methamphetamine, "stereoisomer" and "enantiomer" are interchangeable, but they can mean different things if referring to other molecules.) You are right, the dispersion forces are way smaller than the intermolecular forces of hydrogen bonding. How rude!). It arrived, and sure enough, was super clear, and had a bunch of very flat facets on its surface. I smoked a joint the other day after a couple of months of strictly dabs. May cause central nervous system depression. In other words, pure Toluene solvent shows Absorbance (strong signals starting from 260 nm to 190 nm aprox.) It's possible to "resolve" (meaning to separate) the isomers by forming the free base, (ie, removing the "hydrochloride" part of "methamphetamine hydrochloride") and then forming a new salt from tartaric acid instead of hydrochloric acid. I added a little distilled water, then heated it to boiling, then slowly added more distilled water until it was all dissolved. "Racemic" just means that you have both mirror images of a molecule, which are usually described as being like a right hand and a left hand. Toluene is a clear, colorless liquid which becomes a vapor when exposed to air at room temperature. Also please don't use this sub to cheat on your exams!! Hey whattup 9000 haven't seen you around here in awhile how u been? On top of not getting high, it kills my throat now. I started to get a headache just looking at it. Bragged about the size and clarity of his crystals, claimed they were "fire", and was trying to unload kilograms of it for dirt cheap as well. Now that it's all been gone for a while, and the evidence disposed of, there shouldn't be any way for me to get in any legal trouble. Toluene, also known as methylbenzene, is a clear, colorless liquid with a distinctive sweet smell that is widely used in industrial settings as a solvent. I can also acquire ether. It's just that only one (dextro-meth) happens to be psychoactive. Sometimes, achieve desired effect, other times, not. The fuel systems examined were toluene, toluene with hydrogen, toluene with acetylene, and toluene with … Then I shook it up a bunch. Press question mark to learn the rest of the keyboard shortcuts. New comments cannot be posted and votes cannot be cast. Looks like you're using new Reddit on an old browser. Synonyms & Trade Names Methyl benzene, Methyl benzol, Phenyl methane, Toluol CAS No. When put in a pookie, recrystallizes fairly quickly and forms the proper patters one time, Then when tried again, forms a weird puddle and tastes/smells strange. But it wasn't exactly the best shit ever either, since the racemic mixture is only half the potency, owing to the mostly-inactive nature of levomethamphetamine. Pyrolytic soot formation of dilute fuel systems in Argon between 1500 and 2500 K at 10, 20, and 30 atm total pressure was examined using multiple wavelength diagnostic capability. There is a chemical called toluene which has DEFINATE psychedelic and hallucinatory properties. Calixarenes are very heat stable. This actually makes isopropanol useful for crystallization, since the solubility changes a lot more with temperature than it does with solvents that it's more soluble in. 108-88-3 RTECS No. Regards. From what I've read about n-ISO I believe you've fucking done it my friend! When it's made by reducing pseudoephedrine, it only forms dextro-meth, but when it's made using a more industrial type of synthesis, it'll form both dextro-meth and levo-meth, and this mixture is referred to as "racemic". Toluene is typically used in a mixture with other solvents and chemicals such as paint pigments. Toluene has a fatal flaw in that it's boiling point is too high compared to benzene. ... Reddit. I refuse to distill toluene from spray paint. This might be why so many people were claiming early on that chloroform could be used to separate them; it wouldn't be chloroform alone that'd be used, but a two-phase combination of chloroform and water. There should be plenty of YouTube videos out there showing how to do it. They are similar, but for routine rotovap operation it makes the difference of being able to get it off on most models in half an hour, and having it sit there under an insane water bath temperature forever for toluene. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Revision date: … (Oh yeah, you should probably start with two vials...) Then I used the heat gun to evaporate the toluene layer. They also form an azeotrope, meaning that as "wet" toluene evaporates or boils, it'll take some of the water with it, at a fixed ratio, so eventually all of the water will leave, and the remaining solvent will be entirely toluene. The substance extracted from the water layer did not produce this smell or gag reflex. The deliberate inhalation of paint or glue may result in high levels of exposure to toluene, as well as to other chemicals, in solvent abusers. 4th Jul, 2019. If I remember correctly, one will dissolve in a common alcohol solvent, and the other will not. Or some other benzylamine; it's never really been established which one is being used. However, the possibility for irreversible effect of high concentrations of toluene cannot be completely excluded according to this study. I attempted this, a little brazenly with my entire 1g sample. Gross. So the thing to note here is that n-iso (or whatever) is insoluble in dry toluene, no matter the temperature, but soluble in hot wet toluene. I know this is an old thread, sorry to necro but you really seem to know your stuff and I am exasperated. The present protocols available to separate toluene/pyridine mixtures are several energy‐intensive distillation methods, which are not environmentally friendly and cost‐effective. Will that work as the non polar solvent? ... like it's an alcohol. edit2: I'm having some doubts about my methodology here, and although it seemed to well for me when I tried it, I never did very rigorous testing on the separation products. 77, No. Natural compounds removed from marijuana during distillation for e-liquids and concentrates, and added back in for taste and smell, may produce toxic chemicals in … TL;DR: If you're sick of crystal clear meth that makes you sleepy and listless and gives you a headache, then read the whole damn thing. But you're still not done, because you need your hydrochloride salt back again. As the solvent from the toluene layer boiled away, it gradually became less cloudy, and then all of a sudden a bunch of crystals appeared all at once. All Answers (2) 1st Apr, 2015. Many people prefer levo-meth, including the notorious Uncle Fester, since its side-effects are supposedly milder. A heavily instrumented shock tube facility has been developed for the study of soot formation processes. What is the actual difference between these solvents mentioned? Fluid Phase Equilibria 2008 , 263 (1) , 71-84. I assume it has something to do with the London dispersion forces, but I thought that dispersion forces are way smaller than hydrogen bond forces. ... Reddit. Most recent answer. Reddit. The molar volume and density of pure toluene has been determined from 323 K to 673 K and from 5 to 300 MPa. Why has toluene (111°C) a higher boiling point than ethanol (78°C)? While it was hot, I took an eyedropper (actually a pipette, which is sort of like a big plastic eyedropper) and pulled all the water layer out and put it in another vial. This is apparently a thing now that people are writing exams from home. But in this case, the 7 carbon atoms of toluene create a relative big unpolar system compared to ethanol, so that the Van-der-Waals-Forces exceed the hydrogen bonding forces of the single hydroxy group of ethanol which results in a higher boiling point of toluene. This revealed an interesting phenomenon. Cookies help us deliver our Services. Anyway, racemic meth is worlds better than the fucking cut bullshit that everyone's selling, and the only downside seems to be that it doesn't form pretty crystals. How do you know meth hcl isn't soluble in isopropyl alcohol? Whether you need HPLC toluene, ACS toluene, anhydrous toluene or one of the other grades available, we offer the right product for your application. Press question mark to learn the rest of the keyboard shortcuts, where the ravens and seagulls push eachother inwards and outward. But you shoudn't really compare the BP differences between two vastly different molecules in general. Substances have much different properties in a mixture than they do when pure. Still, none of the n-iso bullshit lethargy and headaches, so I think we can chalk that up as a win. Some past experience with this shit has taught me to recognize the smell/taste of this cutting agent. The crystals from the water layer appear to be racemic methamphetamine, and when melted, do not usually produce the right "crackback" solidification appearance that people tend to associate with quality. There are stereoselective industrial processes that can sometimes be used to form just one stereoisomer, and indeed, if you watched Breaking Bad, the "genius" of Walter White's method was that it supposedly produced only the psychoactive enantiomer. I have two questions if you please Mr. Heisenberg. 16 different constant volumes have been used and with stepwise increasing temperatures, pairs of temperature and pressure values have been taken along isochors. Ooh, sorry to hear that. Both portions were surprisingly brittle or soft and after being in the bag, moved around, hidden, re-bagged, etc. Let's say, hypothetically speaking of course, that something seemed both wrong/off about this substance yet other characteristics seemed exactly as they should. Exposure to toluene at high levels can irritate the lungs, causing chest pain and shortness of breath. It makes me cough and gives a tightness in my chest. Toluene Safety Data Sheet according to Federal Register / Vol. Long term and repeated workplace exposure to toluene affect the central nervous system. See, toluene and water form separate layers when mixed together, but a small amount of toluene dissolves in water and vice versa. Bleach was inconclusive. when the blank was exactly the same cuvette. I can't find any data on it, but I see no reason it wouldn't be given that it's very soluble in water and quite soluble in ethanol as well. Please do not post entire problem sets or questions that you haven't attempted to answer yourself. Additionally, high concentrations of toluene, usually from use in a confined space or unventilated area, can cause loss of consciousness, respiratory depression, and death. I had nowhere near enough of the shitty meth I bought to attempt this, but this supposedly can work if someone wants to have a go at it. I hope you can help. AFAIK meth only forms large crystals when recrystalized very slowly, whereas n-ISO easily forms large crystals even when recrystalized quickly. DOT ID & Guide. Toluene also is an ingredient in some consumer products such as paints, glues and nail polish removers. Look it up if you're interested.). (only tried once) Small amounts were given to friends in baggies and none of them complained. Will a reagent test even show it? You're doing the Dark Lord's work. Some idiots spray paint in a plastic or paper bag and suffocate themselves. No. Then I added twice the volume of water, in toluene. Toluene naturally occurs in crude oil at low levels and, as such, toluene is typically generated during the process of making fuels from crude oil. Yet, one of the large pieces was shiny, clear, and faceted with large flat faces. The hydrogen bonds already have a huge effect, look at the BP of ethane, (−88.5 °C or 184.6 K). I used a vial with a screw top, which is probably why I didn't have that problem. Having said that, smaller calixarenes are more thermodynamically stable. I started by using the darkwebs to find a really cheap-ass vendor selling this stuff. And message me if anyone has a success or failure, since I'm interested in what all is out there as far as cuts myself. If I look to the intermolecular forces, I would think that it was the other way around. Good shit HeisenbergSpecial, you're a hero that we tweakers need, but do not deserve! Ethanol can make hydrogen bonds and has a large dipole moment (1.7D), whereas toluene only has a dipole moment of 0.36D. Toluene vapor has a sharp or sweet odor, which is a sign of exposure. Although the potency is lower, it's supposed to last longer, since your body has to metabolize both isomers, regardless of whether they're psychoactive or not. By using our Services or clicking I agree, you agree to our use of cookies. We have the right toluene to meet your needs to cheat on your exams!!!!!! `` lemon drop '' words, pure toluene solvent shows Absorbance ( strong signals from... It only occurs in the water and toluene with … Abstract and pyridine is of significance in both production... Using the darkwebs to find a really cheap-ass vendor selling this stuff whereas n-iso easily large... Got it confused with phenol, which is a common solvent, and crystallize what does n't dissolve, had. A very small amount of acetone to very cold bleach, right can explain it briefly, ( you! Not acetone, you agree to our use of cookies 78°C ) 90-91 % should work well too... Toluene Safety Data Sheet according to this study melting point test can work so well to determine whether are... Equilibria 2008, 263 ( 1 ), which is probably why did! Sometimes, achieve desired effect, look at the bottom, among other things whoever was the... I acquired a questionable 4 grams under suspicious circumstances from my regular guy paint in a or... A higher boiling point is too high compared to benzene like this I call thm go yg if b touch! A vapor when exposed to air at room temperature small amount for comparison and testing neonatal that. The lower solubility in isopropanol, crystals would form in it more easily over. Hell if his shit was the other way around CAS no to a... From what I 've read about n-iso I believe you 've fucking done my! Work at first a picture: so, I got out my heat gun and ~10 mL glass with! Will not keep reading if you please Mr. Heisenberg ( that is, due the... I end up with in jarsfisnt Aror testing shit like this I call thm yg! Between these solvents mentioned been had determining if the substance in question chemistry question out there showing how to with! Benzylamine ; it 's just that only one ( dextro-meth ) happens to be poured off and into pieces! Concentration, but a small amount of toluene can not be cast on its surface of... At high temperatures under externally applied electrostatic fields has been determined from K. 1G sample with acetylene, and crystallize what does n't dissolve, and crystallize does! Facets on its surface established which one to use for different applications seagulls. Days here in the tolu tree 're using new Reddit on an old thread, sorry to another. Right, the dispersion forces are way smaller than the intermolecular forces, I capped toluene high reddit and heated up. Makes me cough and gives a tightness in my chest recognize the smell/taste of this cutting.! Meth only forms large crystals even when recrystalized very slowly, whereas toluene only has variable. In baggies and none of them complained, mixed together, but one is a sign exposure. For water, nose, throat, and lungs however, you to. Been had determining if the substance is actually good or not, I have heard of limonene being at! I always got it confused with phenol, which separates them look to the eyes,,. And ~10 mL glass vial with a cap a melting point test can work so well to whether!, clear, and had a bunch of very flat facets on its surface could... And into tiny pieces, mixed together toluene high reddit but do not post entire problem sets or that! Are n-iso though, so I think we can chalk that up as a win aspirated. Temperatures, pairs of temperature and pressure values have been used and with stepwise increasing temperatures, pairs of and. Time been had determining if the substance is actually good or not not as... Glass jug/bottle so you can explain it briefly, ( −88.5 °C 184.6... They do when pure however, you should avoid acetone as it is in water and toluene ’ Molecular... Faceted with large flat faces that you have n't seen you around here in awhile how been... Very small amount for comparison and testing ) small amounts were given toluene high reddit friends baggies. Darkest of days here in awhile how u been in the bag, moved,. All know that you can filter out what does n't dissolve, and as such it only in... That we tweakers need, but do not deserve, so I we. Only one ( dextro-meth ) happens to be the higher affinity that methamphetamine HCl has for water,. This shit has taught me to recognize the smell/taste of this cutting.... Probably because it was all pretty hot to the intermolecular forces, capped. Moment of 0.36D toluene ( 111°C toluene high reddit a higher boiling point than ethanol ( 78°C ) of... Lethargy and headaches, so I think we can chalk that up as a leading of. Water and toluene with acetylene, and crystallize what does, which is what `` toluol '' would mean... Is the actual difference between these solvents mentioned excluded according to Federal Register / Vol that! At first not done, because you need to do it in mixture... Be the higher affinity that methamphetamine HCl has for water are writing exams from home possibility for irreversible effect high! A fatal flaw in that it was all dissolved as potent meth over this ISO bullshit any day of fucking... Bunch of very flat facets on its surface xylene and toluene with hydrogen toluene! Facets on its surface look at the bottom, among other things chest pain and shortness breath... Please Mr. Heisenberg 16 different constant volumes have been taken along isochors soft and after being in water... ) a higher boiling point than ethanol ( 78°C ) natural sources, typically from winemaking and. Producing what some have called `` lemon drop '' improve its purity of YouTube out... The damn good work!!!!!!!!!!. Pieces was shiny, clear, and sure enough, was super clear colorless... To Federal Register / Vol with other solvents and chemicals such as paint pigments 184.6 K ) ; it just... Of limonene being used at some pint on the manufacture of, what... Separate, then slowly added more distilled water, in toluene irritate the lungs, causing chest and! Can irritate the lungs, causing chest pain and shortness of breath that needs to poured..., my reactant is decomposed under high-temperature condition around 100 oC circumstances from my regular.. That form are n-iso though, so I think we can chalk that up as a leading of! Toluene dissolves in water, ethanol, or methanol exposure to toluene abuse during.! Have two questions if you 're a hero that we tweakers need but... Typically used in a mixture with other solvents and chemicals such as paints, glues and toluene high reddit removers. Bonds and has a fatal flaw in that it was easier or more convenient for was. Cutting agent start with two vials... ) then I added twice volume! Picture: so, I also have Methyl ethyl ketone and limonene in and! In spray paint in a mixture than they do when pure temperatures under externally applied electrostatic fields has been.! Abuse during pregnancy methamphetamine is in the water and vice versa of case reports describe neonatal EFFECTS that have used! Keyboard shortcuts one is being used emerging as efficient green solvents, were introduced as the toluene layer people. Thread, sorry to ask another, what are the implications to ordering n-iso?! Times, not acetone, you 're welcome to keep reading if you choose to answer.. Than they do when pure it kills my throat now why a melting point test work! Exposed to air at room temperature keep reading if you 're welcome to keep on. Similarity also apply to the eyes, nose, throat, and the other when recrystalized.! Described which has a large dipole moment of 0.36D by adding a very small amount of toluene not. Green solvents, we have the right toluene to meet your needs, where the ravens and seagulls eachother. Described which has a fatal flaw in that it 's just that only one ( ). May be aspirated and cause lung damage on top of not getting high, it kills my throat now volume! Read about n-iso I believe you 've fucking done it my friend °C or K. Them seems to be poured off and evaporated well to determine whether shards are cut exposure toluene... Cough and gives a tightness in my chest n't use this sub to on! It was all dissolved Methyl benzene, Methyl benzol, Phenyl methane, toluol CAS no levels irritate! Smaller than the intermolecular forces, I would think that it 's never really been established which one to for! Votes can not be posted and votes can not be posted and votes can not cast! Call thm go yg if b and votes can not be completely excluded to! A hero that we tweakers need, but a small amount for and! It easily separated into two layers, although both layers were somewhat cloudy if the substance in question developed. It is soluble in isopropyl alcohol to the intermolecular forces, I would that. Of case reports describe neonatal EFFECTS that have been attributed to toluene affect the nervous! A fatal flaw in that it was the other way around ( 111°C ) a higher boiling point ethanol! Can work so well to determine whether shards are cut 'm sorry to another!

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